Acide chromique

Numéro CAS : 7738-94-5

Identification

Description


Numéro UN : UN1755

Formule moléculaire brute : H2CrO4

Principaux synonymes

Noms français :

  • Acide chromique
  • ACIDE CHROMIQUE EN SOLUTION
  • ACIDE CHROMIQUE, EN SOLUTION
  • CHROMIC ACID (H2CrO4)

Noms anglais :

  • CHROMIC (VI) ACID
  • Chromic acid
Commentaires 1 2

Il est important de noter que le produit "acide chromique" (CAS 7738-94-5) existe uniquement en solutions aqueuses.

Utilisation et sources d'émission 1 2

L'acide chromique est utilisé notamment :

  • pour des bains de placage de chrome dans les industries du métal et du plastique
  • pour certaines applications médicales
  • dans des verres colorés
  • dans des encres, des laques ou des peintures

Références

  • ▲1.  Lewis, R.J., Sr., Hawley's condensed chemical dictionary. 14th ed. New York : John Wiley & Sons. (2001).   http://onlinelibrary.wiley.com/book/10.1002/9780470114735
  • ▲2.  Bohnet, M. et al., Ullmann's Encyclopedia of Industrial Chemistry. 7th. Wiley InterScience (John Wiley & Sons). (2003-).   http://www3.interscience.wiley.com (http://www3.interscience.wiley.com/cgi-bin/mrwhome/104554801/HOME)
  • ▲2.  Bohnet, M. et al., Ullmann's Encyclopedia of Industrial Chemistry. 7th. Wiley InterScience (John Wiley & Sons). (2003-).   http://www3.interscience.wiley.com (http://www3.interscience.wiley.com/cgi-bin/mrwhome/104554801/HOME)
  • ▲3.  Haynes, W.M., Bruno, T.J. et Lide, D.R., CRC handbook of chemistry and physics, 2016-2017. 97th ed. Boca Raton (FL) : CRC Press. (2016). [RS-014001]   http://www.hbcpnetbase.com/
  • ▲4.  Cairelli, S.G., Ludwig, H.R. et Whalen, J.J., Documentation for immediately dangerous to life or health concentrations (IDLHS). Springfield (VA) : NTIS. (1994). PB-94-195047. [RM-515102]   http://www.cdc.gov/niosh/idlh/intridl4.html
  • ▲5.  Perry, Dale L., Handbook of Inorganic Compounds. 2ème éd. Boca Raton, FL : CRC Press. (2011). [MO-000119]   www.taylorandfrancis.com httpL//www.crcpress.com
  • ▲6.  Drolet, D. et Beauchamp, G, Guide d'échantillonnage des contaminants de l'air en milieu de travail. Études et recherches / Guide technique, 8ème éd. revue et mise à jour. Montréal : IRSST. (2012). T-06. [MO-220007]   http://www.irsst.qc.ca
    http://www.irsst.qc.ca/files/documents/PubIRSST/t-06.pdf
  • ▲7.  Truchon, G., Guide de surveillance biologique : prélèvement et interprétation des résultats. Études et recherches / IRSST, 6ème éd. Montréal : IRSST. (2004). T-03.   http://www.irsst.qc.ca/files/documents/PubIRSST/T-03.pdf
    http://www.irsst.qc.ca
  • ▲8.  Règlement sur la santé et la sécurité du travail [S-2.1, r. 13]. Québec : Éditeur officiel du Québec. [RJ-510071]   http://legisquebec.gouv.qc.ca/fr/ShowDoc/cr/S-2.1,%20r.%2013
  • ▲8.  Règlement sur la santé et la sécurité du travail [S-2.1, r. 13]. Québec : Éditeur officiel du Québec. [RJ-510071]   http://legisquebec.gouv.qc.ca/fr/ShowDoc/cr/S-2.1,%20r.%2013
  • ▲9.  Agency for toxic Substances and Disease Registry, Toxicological profile for chromium. Atlanta : ATSDR. (2000). Update.   https://www.atsdr.cdc.gov/ToxProfiles/tp7.pdf
    http://www.atsdr.cdc.gov/toxprofiles/
  • ▲9.  Agency for toxic Substances and Disease Registry, Toxicological profile for chromium. Atlanta : ATSDR. (2000). Update.   https://www.atsdr.cdc.gov/ToxProfiles/tp7.pdf
    http://www.atsdr.cdc.gov/toxprofiles/
  • ▲10.  American Conference of Governmental Industrial Hygienists, «Chromium and inorganic compounds.» In: Documentation of the threshold limit values and biological exposure indices / Documentation of TLV's and BEI's. Cincinnati, Ohio : ACGIH. (2018). Publication #0100Doc.   http://www.acgih.org
  • ▲11.  Grant, W.M. et Schuman, J.S., Toxicology of the eye : effects on the eyes and visual systems from chemicals, drugs, metals and minerals, plants, toxins and venoms; also, systemic side effects from eye medications. Vol. 1, 4th ed. Springfield (ILL.) : Charles C. Thomas. (1993). [RM-515030]
  • ▲12.  Criteria group for occupational standards, «Scientific basis for Swedish occupational standards XXI. Consensus report for chromium and chromium compounds.» Arbete och Hälsa. Vol. VI, no. 22, p. 18-40. (2000). [AP-063399]   https://gupea.ub.gu.se/dspace/handle/2077/3194?locale=en
    http://www.inchem.org/documents/kemi/kemi/ah2000_22.pdf
  • ▲12.  Criteria group for occupational standards, «Scientific basis for Swedish occupational standards XXI. Consensus report for chromium and chromium compounds.» Arbete och Hälsa. Vol. VI, no. 22, p. 18-40. (2000). [AP-063399]   https://gupea.ub.gu.se/dspace/handle/2077/3194?locale=en
    http://www.inchem.org/documents/kemi/kemi/ah2000_22.pdf
  • ▲13.  IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, Chromium, nickel and welding. IARC monographs on the evaluation of carcinogenic risks to humans, Vol. 49. Lyon : International Agency for Research on Cancer. (1990).   https://monographs.iarc.fr/wp-content/uploads/2018/06/mono49.pdf
    http://www.iarc.fr
  • ▲14.  Lauwerys, R. et al., Toxicologie industrielle et intoxications professionnelles. 5ème éd. Issy-les-Moulineaux Cedex : Elsevier Masson SAS. (2007). [RM-514015]
  • ▲14.  Lauwerys, R. et al., Toxicologie industrielle et intoxications professionnelles. 5ème éd. Issy-les-Moulineaux Cedex : Elsevier Masson SAS. (2007). [RM-514015]
  • ▲15.  International Programme on Chemical Safety (IPCS), Inorganic Chromium (VI) compounds. Concise International Chemical Assessment Document , Vol. 78. World Health Organisation. (2013). ISBN 978 92 4 1530781.   http://www.inchem.org/documents/cicads/cicads/cicad_78.pdf
  • ▲16.  Hartwig A. et MAK commission 2016, Chromium(VI) compounds (inhalable fraction) [MAK Value Documentation, 2012].. The MAK Collection for Occupational Health and Safety, Vol. 1. Wiley-VCH. 2442-2524.   http://onlinelibrary.wiley.com/doi/10.1002/3527600418.mb1854029stae5316/pdf
  • ▲17.  Royle H., «Toxicity of Chromic Acid in the Chromium Plating Industry.» Environmental Research. Vol. 10, p. 39-53,141-163. (1975). [AP-020917]
  • ▲18.  Basketter, D.A. et al., «Nickel, cobalt and chromium in consumer products : a role in allergic contact dermatitis.» Contact Dermatitis. Vol. 28, p. 15-25. (1993).
  • ▲19.  Burrows, D., «Chromate dermatitis.» In: Occupational and industrial dermatology. , p. 406-420. Chicago : Year Book Medical. (1987). [MO-002907]
  • ▲20.  Bernstein, I.L. et al., Asthma in the workplace : and related conditions. 3 éd. New York : Taylor & Francis. (2006).   www.taylorandfrancis.com
  • ▲20.  Bernstein, I.L. et al., Asthma in the workplace : and related conditions. 3 éd. New York : Taylor & Francis. (2006).   www.taylorandfrancis.com
  • ▲21.  Rietschel,, R.L. et Fowler Jr., J.F., Fisher's contact dermatitis. 6ème. Hamilton (Ontario) : BC Decker Inc.. (2008). [RM-015084]
  • ▲22.  Malo, J.-L., Chang-Yeung, M. et Bernstein, D.I., Asthma in the workplace. 4th ed. New York : CRC Press / Taylor @ Francis Group. (2013). [MO-002878]   http://www.taylorandfrancis.com
    http://www.crcpress.com
  • ▲23.  Dupas D., Fiche d'Allergologie-pneumologie Professionnelle. Allergies respiratoire professionnelle aux sels de chrome.. Documents pour le Médecin du Travail, Vol. TR 45. Institut national de recherche et de sécurité. (2009).   http://www.rst-sante-travail.fr/rst/pages-article/ArticleRST.html?ref=RST.TR%2045
  • ▲24.  Crepy M.N, Fiche d'allergologie-dermatologie professionnelle TA 85. Dermatose professionnelles allergiques aux métaux. Deuxième partie: allergie de contact aux composés du chrome. Documents pour le médecin du travail. Institut national de recherche et de sécurité. (2010).   http://www.rst-sante-travail.fr/rst/pages-article/ArticleRST.html?ref=RST.TA%2085
  • ▲25.  Trivedi, B. et al., «Embryotoxicity and fetotoxicity of orally administred hexavalent chromium in mice.» Reproductive Toxicology. Vol. 3, p. 275-278. (1989). [AP-046466]
  • ▲26.  Junaid, M., Murthy, R.C. et Saxena, D.K., «Embryotoxicity of orally administered chromium in mice : Exposure during the period of organogenesis.» Toxicology Letters. Vol. 84, p. 143-148. (1996). [AP-068078]
  • ▲27.  Junaid, M., Murthy, R.C. et Saxena, D.K., «Embryo- and fetotoxicity of chromium in pregestationally exposed mice.» Bulletin of Environmental Contamination and Toxicology. Vol. 57, p. 327-334. (1996). [AP-050498]
  • ▲28.  Glaser U et al., «Inhalation Studies with Wistar Rats and Pathophysiological Effects of Chromium..» In: Berlin, Federal Environment Agency. , p. 156. (1984). Report D-1 UFOPLAN FTE 10606007/2.
  • ▲29.  De Flora S., Iltcheva M. et Blansky R.M., «Oral Chromium (VI) does not Affect the Frequency of Micronuclei in Hematopoietic Cells of Adult Mice and Transplacental Foetus..» Mutation Research. Vol. 610, p. 38-47. (2006).
  • ▲30.  Kanojia R.K., Junaid M. et Murthy R.C., «Chromium Induced Teratogenicity in Female Rat.» Toxicology Letters. Vol. 89, p. 207-213. (1996). [AP-051557]
  • ▲31.  Elsaieed, E.M. et Nada, S.A., «Teratogenicity of hexavalent chromium in rats and the beneficial role of ginseng.» Bulletin of environmental contamination and toxicology. Vol. 68, no. 3, p. 361-368. (2002). [AP-001027]
  • ▲32.  Kanojia, R.K., Junaid, M. et Murthy, R.C., «Embryo and fetotoxicity of hexavalent chromium: a long-term study.» Toxicology letters. Vol. 95, no. 3, p. 165-172. (May 1998). [AP-001028]
  • ▲33.  Hjollund, N., Bonde, J. et Hanse, K., «Male-mediated risk of spontaneous abortion with reference to stainless steel welding», Scandinavian Journal of Work, Environment & Health, 21, 4, 1995, 272-276 [AP-047863]
  • ▲34.  Jelnes, J.E. et Knudsen, L.E., «Stainless steel welding and semen quality. In : Symposium on the assessment of reproductive hazards in the workplace.» Reproductive toxicology. Vol. 2, no. 3-4, p. 213-215. (1988). Pergamon Press. [MO-013932]
  • ▲35.  Rachootin, P. et Olsen, J., «The risk of infertuility and delayed conception associated with exposures in the danish workplace .» Journal of Occupational Medicine. Vol. 25, no. 2, p. 394-402. (1983). [AP-052412]
  • ▲36.  Chowdhury, A.R. et Mitra, C., «Spermatogenic and steroidogenic impairment after chromium treatment in rats.» Indian Journal of Experimental Biology. Vol. 33, p. 480-484. (1995). [ap-068076]
  • ▲37.  Elbetieha, A. et Al-Hamood, M.H., «Long-term exposure of male and female mice to trivalent and hexavalent chromium compounds: effect on fertility.» Toxicology. Vol. 116, p. 39-47. (1997). [AP-053327]
  • ▲38.  Li, H., Chen, Q. et Li, S., «Effect of Cr(VI) exposure on sperm quality: human and animal studies..» Annals of Occupational Hygiene. Vol. 45, no. 7, p. 505-511. (2001).
  • ▲39.  Zahid, Z. R., Al-Hakkak, Z. S. et Kadhim, A H. H., «Comparative effects of trivalent and hexavalent chromium on spermatogenesis of the mouse.» Toxicol Environ Chem. Vol. 25, p. 131-136. (1990). [AP-046288]
  • ▲40.  Health council of the Netherlands: Committee for compounds toxic to reproduction, «Chromium VI and its compounds. Evaluation of the effects on reproduction, recommendation for classification.» In: The Hague: Health Concil of the Netherlands. (2001).   https://www.gezondheidsraad.nl/sites/default/files/0101osh.pdf
  • ▲41.  Murthy R.C., Junaid M. et Saxena D.K., «Ovarian Dysfunction in mice following chromium (VI) exposure .» Toxicology Letters. Vol. 89, p. 147-154. (1996). [AP-050889]
  • ▲42.  Subramanian S. et al., «Reproductive Toxicity of Chromium in Adult Bonnet Monkeys (Macaca radiata Geoffrey). Reversible Oxidative Stress in the Semen..» Toxicology and Applied Pharmacology. Vol. 215, p. 237-249. (2006).
  • ▲43.  Mortensen J.T., «Risk for Reduced Sperm Quality Among Metal Workers, with Special Reference to Welders.» Scandinavian Journal of Work, Environment & Health. Vol. 14, p. 27-30. (1988). [AP-017590]
  • ▲44.  Samuel J.B. et al., «Lactational Hexavalent Chromium Exposure-Induced Oxidative Stress in Rat Uterus is Associated with Delayed Puberty and Impaired Gonadotrophin Levels.» Human & Experimental Toxicology. Vol. 30, no. 2, p. 91-101. (2011).
  • ▲45.  Al-Hamood M.H., Elbetieha A. et Bataineh H., «Sexual Maturation and Fertility of Male and Female Mice Exposed Prenatally and Postnatally to Trivalent and Hexavalent Chromium Compounds..» Reproduction, fertility, and developmment . Vol. 10, p. 179-183. (1998). [AP-059602]
  • ▲46.  Report on Carcinogens, 14th edition. Research Triangle Park, NC : U.S. Department of Health and Human Services, Public Health Service, National Toxicology Program. (2016).   https://ntp.niehs.nih.gov/pubhealth/roc/index-1.html
  • ▲47.  American Conference of Governmental Industrial Hygienists, Documentation of the threshold limit values and biological exposure indices / Documentation of TLV's and BEI's. 7th ed. Cincinnati, Ohio : ACGIH. (2001-). Publication #0100Doc. [RM-514008]   http://www.acgih.org
  • ▲47.  American Conference of Governmental Industrial Hygienists, Documentation of the threshold limit values and biological exposure indices / Documentation of TLV's and BEI's. 7th ed. Cincinnati, Ohio : ACGIH. (2001-). Publication #0100Doc. [RM-514008]   http://www.acgih.org
  • ▲48.  IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, A Review of Human Carcinogens: Arsenic, Metals, Fibres, and Dusts. IARC monographs on the evaluation of carcinogenic risks to humans, Vol. 100C. Lyon : International Agency for Research on Cancer. (2012).   http://monographs.iarc.fr/
    http://monographs.iarc.fr/ENG/Monographs/vol100C/mono100C.pdf
  • ▲48.  IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, A Review of Human Carcinogens: Arsenic, Metals, Fibres, and Dusts. IARC monographs on the evaluation of carcinogenic risks to humans, Vol. 100C. Lyon : International Agency for Research on Cancer. (2012).   http://monographs.iarc.fr/
    http://monographs.iarc.fr/ENG/Monographs/vol100C/mono100C.pdf
  • ▲49.  American Conference of Governmental Industrial Hygienists, 2019 TLVs® and BEIs® : threshold limit values for chemical substances and physical agents and biological exposure indices. Cincinnati (OH) : ACGIH. (2019). [NO-003164]   http://www.acgih.org
  • ▲50.  Deutsche Forschungsgemeinschaft, MAK value documentation : Chromium and its compounds. The MAK Collection for Occupational Health and Safety. Weinheim : Wiley-VCH. (1992).   http://onlinelibrary.wiley.com/doi/10.1002/3527600418.mb1854029stae0003/pdf
  • ▲51.  Blankenship L.J., Carlisle D.L. et Wise J.P., «Induction of Apoptotic Cell Death by Particulate Lead Chromate: Differential Effects of Vitamins C and E on Genotoxicity and Survival.» Toxicology and Applied Pharmacology. Vol. 146, p. 270-280. (1997).
  • ▲52.  Seoane A.I. et Dulout F.N., «Contribution to the Validation of the Anaphase-telophase Test: Aneugenic and Clastogenic Rffects of Cadmium sulfate, Potassium dichromate and Nickel chloride in Chinese Hamster Ovary Cells.» Genetics and Molecular Biology. Vol. 22, no. 4, p. 551-555. (1999).
  • ▲53.  Occidental Chem. Corp., Initial submission : CRO3 oral and dermal studies of chromic oxide in rats (final report) . (1988). Microfiche : OTS0537097
  • ▲53.  Occidental Chem. Corp., Initial submission : CRO3 oral and dermal studies of chromic oxide in rats (final report) . (1988). Microfiche : OTS0537097
  • ▲54.  Canada. Ministère des transports, Règlement sur le transport des marchandises dangereuses. Ottawa : Éditions du gouvernement du Canada. (2014). [RJ-410222]   http://www.tc.gc.ca/fra/tmd/clair-menu-497.htm
    http://www.tc.gc.ca/tmd/menu.htm
  • ▲55.  BGIA-Gestis, Information system on hazardous substances of the Berufsgenossenschaften. Sankt Augustin, Germany : Berufsgenossenschaftliches Institut.   http://www.hvbg.de/e/bia/fac/stoffdb/index.html
  • ▲56.  Cloutier, M. et Cushmac, G., Emergency Response Guidebook 2012. États-Unis : U.S. DOT’s Pipeline and Hazardous Materials Safety Administration. (2012).
  • ▲57.  Independent Environmental Technical Evaluation Group (IETEG), Chromium (VI) Hanbook. CRC Press. (2005). [MO-028886]
  • ▲58.  Asthmagen? : critical assessments of the evidence for agents implicated in occupational asthma. Health and Safety Executive. Sudbury, Suffolk, G.B. : HSE Books. (2001). [MO-020018]   http://www.hse.gov.uk/asthma/asthmagen.pdf
  • ▲59.  Williams, C.D., «Asthma related to chromium compounds. Reports of two cases and review of the literature on chromate diseases.» North Carolina Medical Journal. Vol. 30, p. 482-491. (1969). [AP-047653]
  • ▲60.  Joules, H., «Asthma from sensitisation to chromium.» Lancet. Vol. 2, p. 182-183. (1932). [AP-024536]
  • ▲61.  Bureau européen des substances chimiques, European Union Risk Assessment Report : Chromium trioxide, sodium chromate, sodium dichromate, ammonium dichromate and potassium dichromate. 3rd Priority List, Vol. 53. Luxembourg : Office for Official Publications of the European Communities. (2005). EUR 21508 EN.   http://echa.europa.eu/documents/10162/3be377f2-cb05-455f-b620-af3cbe2d570b
  • ▲62.  Agency for Toxic Substances and Disease Registry, Toxicological profile for chromium. Atlanta, GA : ATSDR. (2000). Microfiche : PB93-182434, ATSDR/TP-92/08   http://www.atsdr.cdc.gov/toxprofiles/
  • ▲63.  The health council of the Netherlands, Chromium VI and its compounds: Evaluation of the effects on reproduction, recommendation for classification. The Hague. (2001).   https://www.gezondheidsraad.nl/sites/default/files/0101osh.pdf
    http://www.gezondheidsraad.nl/en/publications/healthy-working-conditions

Autres sources d'information

  • American Conference of Governmental Industrial Hygienists, 2010 TLVs and BEIs with 7th edition documentation CD-ROM. Cincinnati, OH : ACGIH. (2010). Publication 0111CD. [CD-120061]   http://www.acgih.org
  • Allan, R.E. et al., Patty's industrial hygiene and toxicology : toxicology. Vol. 2, part A, 4th ed. New York; Toronto : Wiley. (1993-1994).
  • Friberg, L., Norsberg, G.F. et Vouk, V.B., Handbook on the toxicology of metals. 3nd ed.. New York : Elsevier. (2007). [RM-515001]
  • Vyskocil, A., Viau, C. et Brodeur, J., Recherche d'informations sur la classe de produits chrome VI : Rapport final présenté à la CSST. Montréal : Département de Médecine du travail et d'hygiène du milieu, Université de Montréal. (1995). [MO-018723]
  • JOURNAL OF THE AMERICAN MEDICAL ASSOCIATION, VOL.169, 1959, P. 566-569 [AP-046854]
  • Dreisbach, R.H. et Robertson, W.O., Handbook of poisoning: prevention diagnosis & treatment. 12th ed. Norwalk, Conn. : Appleton & Lange. (1987). [RM-515008]
  • Agency for Toxic Substances and Disease Registry, Toxicological profile for chromium. Atlanta, GA : ATSDR. (2000). Microfiche : PB93-182434, ATSDR/TP-92/08   http://www.atsdr.cdc.gov/toxprofiles/
  • Boloorchi, A. et al., «Chromic acid burns: systematic prevention of systemic toxicity.» Annales de chirurgie plastique et esthetique. Vol. 52, no. 6, p. 621-623. (2007).

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