WHMIS (N,N-Dimethylcarbamoyl chloride)

Workplace Hazardous Materials Information System

WHMIS 2015 classification - Note to reader

• Flammable liquids - Category 41
• Flash point = 68,3 °C Tag closed cup

• Acute toxicity - oral - Category 42 3 4

• Acute toxicity - inhalation - Category 23 4 5 6 7
• Releases a toxic gas upon contact with water: Hydrogen chloride

• Skin corrosion/irritation - Category 22 8

• Serious eye damage/eye irritation - Category 22 8

• Carcinogenicity - Category 1B2 9 10 11

• Specific target organ toxicity - single exposure (respiratory tract irritation) - Category 3 - Respiratory tract irritation2 8

Danger

Combustible liquid (H227)
Harmful if swallowed (H302)
On contact with water releases gases which are fatal if inhaled; Fatal if inhaled (H330)
Causes skin irritation (H315)
Causes serious eye irritation (H319)
May cause cancer (H350)
May cause respiratory irritation (H335)

Ingredient disclosure

Comments: This product could be corrosive to metals, please contact the supplier for additionnal information.

References

• ▲1.  United States Coast Guard et Department of Transport, Chemical Hazards Response Information System (CHRIS). Washington, D. C. : United States Coast Guard. (1999).   http://www.suttercountyfire.org/YSHMRT/CHRIS%20MANUAL%20CIM_16465_12C.pdf
• ▲2.  American Conference of Governmental Industrial Hygienists, Documentation of the threshold limit values and biological exposure indices / Documentation of TLV's and BEI's. 7th ed. Cincinnati, Ohio : ACGIH. (2001-). Publication #0100Doc. [RM-514008]   http://www.acgih.org
• ▲3.  National Institute for Occupational Safety and Health, RTECS (Registry of Toxic Effects of Chemical Substances). Hamilton (Ont) : Canadian Centre for Occupational Health and Safety.   http://ccinfoweb.ccohs.ca/rtecs/search.html
• ▲4.  Centre canadien d'hygiène et de sécurité au travail, CHEMINFO, Hamilton, Ont. : Canadian Centre for Occupational Health and Safety   http://ccinfoweb.ccohs.ca/cheminfo/search.html
• ▲5.  United States. National Ocean Service. Office of Response and Restoration., Computer aided management of emergency operations chemicals (CAMEO chemicals) : online database of hazardous materials. USA : National Oceanic and Atmospheric Administration.   http://cameochemicals.noaa.gov/search/simple
  http://cameochemicals.noaa.gov/
• ▲6.  Pohanish, R.P. et Greene, S.A., Wiley guide to chemical incompatibilities. 3ème éd. New Jersey : John Wiley & Sons Inc. (2009). [RR-015033]   www.wiley.com
• ▲7.  New Jersey Department of Health and Senior Services, Hazardous substance fact sheet : Dimethylcarbamoyl chloride. Right to Know Program. Trenton, NJ. (2008). RTK 0746.   http://nj.gov/health/eoh/rtkweb/documents/fs/0746.pdf
• ▲8.  Malo, J. L., Cartier, A. et Boulet, L. P., «Occupational asthma in sawmills of eastern Canada and United States.» Journal of Allergy and Clinical Immunology. Vol. 18, no. 3, p. 392-398. (1986). [AP-018310]
• ▲9.  IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, Overall evaluations of carcinogenicity : an updating of IARC monographs volumes 1-42. IARC monographs on the evaluation of carcinogenic risks to humans, Supplement 7. Lyon : International Agency for Research on Cancer. (1987).   https://monographs.iarc.fr/wp-content/uploads/2018/06/Suppl7.pdf
  http://monographs.iarc.fr/
• ▲10.  IARC Working Group on the Evaluation of Carcinogenic Risks of Chemical to Man, Some Carbamates, Thiocarbamates and Carbazides. IARC monographs on the evaluation of carcinogenic risks of chemical to man, Vol. 12. Lyon : International Agency for Research on Cancer. (1976).   https://monographs.iarc.fr/wp-content/uploads/2018/06/mono12.pdf
  http://www.iarc.fr
• ▲11.  IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, Re-evaluation of some organic chemicals, hydrazine and hydrogen peroxide : part 1. IARC monographs on the evaluation of carcinogenic risks to humans, Vol. 71. Lyon : International Agency for Research on Cancer. (1999).   https://monographs.iarc.fr/wp-content/uploads/2018/06/mono71.pdf http://www.iarc.fr

The [number] refers to the Information SST database of the CNESST Documentation Center.