WHMIS (Aniline)

Workplace Hazardous Materials Information System

WHMIS 1988 classification - Note to reader
Update: 2006-02-23
  • WHMIS pictogram : Flame

    B3

  • WHMIS pictogram : Skull and crossbones

    D1A, D2B

B3
  • Combustible liquid 1
  • flash point = 70 °C closed cup (non reported method)
D1A
  • Very Toxic Material Causing Immediate and Serious Toxic Effects 2
  • Transportation of Dangerous Goods: class 6.1 group II
D2B
  • Toxic Material Causing Other Toxic Effects 3 4 5 6
  • eye irritation in animals; mutagenicity in animals

Disclosure at 1,0% according to the Ingredient disclosure list

WHMIS 2015 classification - Note to reader
Update: 2015-08-19

  • Flammable liquids - Category 47
    • Flash point = 70 °C Tag closed cup
  • Acute toxicity - oral - Category 48 9 10 11 12 13
  • Acute toxicity - dermal - Category 39 12 13
  • Acute toxicity - inhalation - Category 29 11 12 13 14
  • Serious eye damage/eye irritation - Category 2A11 12 13 15
  • Germ cell mutagenicity - Category 23 8 11 13
  • Specific target organ toxicity - single exposure - Category 18 12 13
  • Specific target organ toxicity - repeated exposure - Category 18 11 12 13

  • GHS pictogram : Skull and crossbones

  • GHS pictogram : Exclamation mark

  • GHS pictogram : Health hazard

Danger

Combustible liquid (H227)
Harmful if swallowed (H302)
Toxic in contact with skin (H311)
Fatal if inhaled (H330)
Causes serious eye irritation (H319)
May cause allergic skin reaction (H317)
Suspected of causing genetic defects (H341)
Causes damage to organs (H370)
Causes damage to organs through prolonged or repeated exposure (H372)

Ingredient disclosure

References

  • ▲1.  National Fire Protection Association, Fire protection guide to hazardous materials. 12th ed. Quincy, Mass. : NFPA. (1997). [RR-334001]   http://www.nfpa.org/
  • ▲2.  Canada. Ministère des transports, Règlement sur le transport des marchandises dangereuses. Ottawa : Éditions du gouvernement du Canada. (2014). [RJ-410222]   http://www.tc.gc.ca/fra/tmd/clair-menu-497.htm
    http://www.tc.gc.ca/tmd/menu.htm
  • ▲3.  IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, Overall evaluations of carcinogenicity : an updating of IARC monographs volumes 1-42. IARC monographs on the evaluation of carcinogenic risks to humans, Supplement 7. Lyon : International Agency for Research on Cancer. (1987). [MO-011531]   http://www.iarc.fr ou
    http://monographs.iarc.fr/
  • ▲4.  IARC Working Group on the Evaluation of the Carcinogenic Risks of Chemicals to Humans, Chemicals industrial processes and industries associated with cancer in humans. IARC monographs, volumes 1 to 29. IARC monographs on the evaluation of the carcinogenic risk of chemicals to humans, Supplement 4. Lyon : International Agency for Research on Cancer. (1982). [MO-002941]   http://www.iarc.fr
  • ▲5.  Allied Chem. Corp., Toxicity tests on BC-55379, aniline. (1983). Microfiche : OTS0215155, EPA/OTS; Doc #878221061
  • ▲6.  Chemfirst Inc., Toxicity testing of aniline, n-isoprophy aniline and meta phenylene diamine for the first chemical corporation, with cover letter dated 7/24/1998 (sanitized). (1984). Microfiche : OTS0559504, EPA/OTS; Doc #86980000169S
  • ▲7.  Pohanish, R.P. et Greene, S.A., Hazardous materials handbook. New York (NY) : Van Nostrand Reinhold. (1996). [RR-515125]
  • ▲8.  American Conference of Governmental Industrial Hygienists, Documentation of the threshold limit values and biological exposure indices / Documentation of TLV's and BEI's. 7th ed. Cincinnati, Ohio : ACGIH. (2001-). Publication #0100Doc. [RM-514008]   http://www.acgih.org
  • ▲9.  National Institute for Occupational Safety and Health, RTECS (Registry of Toxic Effects of Chemical Substances). Hamilton (Ont) : Canadian Centre for Occupational Health and Safety.   http://ccinfoweb.ccohs.ca/rtecs/search.html
  • ▲10.  National Library of Medicine, The Hazardous Substances Data Bank (HSDB). Hamilton (Ont.) : Canadian Centre for Occupational Health and Safety.   http://www.ccohs.ca/
  • ▲11.  Centre canadien d'hygiène et de sécurité au travail, CHEMINFO, Hamilton, Ont. : Canadian Centre for Occupational Health and Safety   http://ccinfoweb.ccohs.ca/cheminfo/search.html
  • ▲12.  France. Institut national de recherche et de sécurité, Fiche toxicologique no 19 : Aniline. Cahiers de notes documentaires. Paris : INRS. (2010). [RE-005509]   http://www.inrs.fr/publications/bdd/fichetox.html
    http://www.inrs.fr/publications/bdd/fichetox/fiche.html?refINRS=FICHETOX_19
  • ▲13.  BGIA-Gestis, Information system on hazardous substances of the Berufsgenossenschaften. Sankt Augustin, Germany : Berufsgenossenschaftliches Institut.   http://www.hvbg.de/e/bia/fac/stoffdb/index.html
  • ▲14.  Carpenter, C.P., Smyth, H.F. et Pozzani, V.C., «The assay of acute vapor toxicity, and the grading and interpretation of results on 96 chemical compounds.» Journal of Industrial Hygiene and Toxicology. Vol. 31, no. 6, p. 343-346. (1949). [AP-023681]
  • ▲15.  ECHA (European Chemicals Agency) , Information on Chemicals (REACH). Helsinki, Finland.   http://echa.europa.eu/information-on-chemicals/registered-substances
  • ▲16.  Kligman, A.M., «The identification of contact allergens by human assay. III. The maximization test : a procedure for screening and rating contact sensitizers.» Journal of Investigative Dermatology. Vol. 47, no. 5, p. 393-409. (1966). [AP-022756]
  • ▲17.  Malten, K.E. et Kuiper, J.P., «Contact allergic reactions in 100 selected patients with ulcus cruris.» Vasa. Vol. 14, no. 4, p. 340-345. (1985). [AP-023377]
  • ▲18.  Kimber, I. et al., «The local lymph node assay : developments and applications.» Toxicology. Vol. 93, no. 1, p. 13-31. (1994). [AP-063496]

The [number] refers to the ISST database of the CSST Documentation Center.